Publication | Closed Access
The first Janus [2]rotaxane
88
Citations
3
References
2000
Year
Nmr Methodsα-Cyclodextrin 1DerivativesEngineeringHistorical ArchaeologyHeterocyclicDiversity Oriented SynthesisOrganic ChemistrySynthetic ChemistryChemistryLanguage StudiesBis-azo CouplingClassicsBiomolecular Engineering
The first Janus [2]rotaxane 3 has been synthesized by bis-azo coupling of 2-naphthol-3,6-disulfonic acid with a Janus [2]pseudorotaxane 2 prepared by dimerization of 6-O-[(4-aminophenylazo)phenyl]-permethylated α-cyclodextrin 1 and characterized by MALDI-TOF-MS and 1H NMR methods.
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