An aqueous non-heme Fe(iv)oxo complex with a basic group in the second coordination sphere - Concepedia

Concepedia

Abstract

The Fe(IV)oxo complex of a coordinatively flexible multidentate mono-carboxylato ligand is obtained by the one electron oxidation of a low spin Fe(III) precursor in water.

References

	Year	Citations
Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)=O Complex Jan‐Uwe Rohde, Jun-Hee In, Mi Hee Lim, Science Inorganic ChemistryBioorganic ChemistryEngineeringBiochemistryNatural Sciences	2003	910
Aqueous Fe<sup>IV</sup>O: Spectroscopic Identification and Oxo‐Group Exchange Oleg Pestovsky, Sebastian A. Stoian, Emile L. Bominaar, Angewandte Chemie International Edition	2005	381
Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)Fe<sup>III</sup>(N<sub>3</sub>)]<sup>+</sup> and Ozonolysis of [(cyclam-acetato)Fe<sup>III</sup>(O<sub>3</sub>SCF<sub>3</sub>)]<sup>+</sup> in Water/Acetone Mixtures Craig A. Grapperhaus, Bernd Mienert, Eckhard Bill, Inorganic Chemistry Inorganic ChemistryChemical EngineeringEngineeringPhotoredox ProcessPhotochemistry	2000	305
Structures of Nonheme Oxoiron(<scp>IV</scp>) Complexes from X‐ray Crystallography, NMR Spectroscopy, and DFT Calculations Eric J. Klinker, József Kaizer, William W. Brennessel, Angewandte Chemie International Edition Inorganic CompoundInorganic ChemistryEngineeringNmr SpectroscopyCoordination Complex	2005	263
Formation, Structure, and EPR Detection of a High Spin Fe<sup>IV</sup>—Oxo Species Derived from Either an Fe<sup>III</sup>—Oxo or Fe<sup>III</sup>—OH Complex David C. Lacy, Rupal Gupta, Kari L. Stone, Journal of the American Chemical Society	2010	246
Performance of Nonrelativistic and Quasi-Relativistic Hybrid DFT for the Prediction of Electric and Magnetic Hyperfine Parameters in<sup>57</sup>Fe Mössbauer Spectra Sebastian Sinnecker, Leonardo D. Slep, Eckhard Bill, Inorganic Chemistry EngineeringMagnetic ResonanceIron ComplexesComputational ChemistryChemistry	2005	228
Mechanism of Taurine: α‐Ketoglutarate Dioxygenase (TauD) from <i>Escherichia coli</i> J. Martin Bollinger, John C. Price, Lee M. Hoffart, European Journal of Inorganic Chemistry BiosynthesisAldehyde DehydrogenaseHigh‐valent Iron IntermediateBiochemistryCellular Enzymology	2005	195
The Crystal Structure of a High-Spin Oxoiron(IV) Complex and Characterization of Its Self-Decay Pathway Jason England, Yisong Guo, Erik R. Farquhar, Journal of the American Chemical Society	2010	177
Proton‐ and Reductant‐Assisted Dioxygen Activation by a Nonheme Iron(II) Complex to Form an Oxoiron(IV) Intermediate Aurore Thibon, Jason England, Marlène Martinho, Angewandte Chemie International Edition Fe ComplexInorganic ChemistryFe MagentaEngineeringBiochemistry	2008	164
Modeling the <i>cis</i>‐Oxo‐Labile Binding Site Motif of Non‐Heme Iron Oxygenases: Water Exchange and Oxidation Reactivity of a Non‐Heme Iron(IV)‐Oxo Compound Bearing a Tripodal Tetradentate Ligand Chemistry - A European Journal EngineeringChemistryRedox BiologyInorganic CompoundWater Exchange	2011	113

Page 1