Concepedia

An aqueous non-heme Fe(iv)oxo complex with a basic group in the second coordination sphere

Mads Sørensen Vad, Anders Lennartson, A. Nielsen, Jeffrey R. Harmer, John E. McGrady, Cathrine Frandsen, Steen Mørup, Christine J. McKenzie

Chemical Communications · 2012 · 31 citations · 21 references

DOIFull text

Open access

Concepts

Abstract

The Fe(IV)oxo complex of a coordinatively flexible multidentate mono-carboxylato ligand is obtained by the one electron oxidation of a low spin Fe(III) precursor in water.

References

21

Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)=O Complex

Jan‐Uwe Rohde, Jun-Hee In, Mi Hee Lim et al. · Science · 2003 · 924 citations

, , +17

Aqueous Fe<sup>IV</sup>O: Spectroscopic Identification and Oxo‐Group Exchange

Oleg Pestovsky, Sebastian A. Stoian, Emile L. Bominaar et al. · Angewandte Chemie International Edition · 2005 · 388 citations

, , +16

Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)Fe<sup>III</sup>(N<sub>3</sub>)]<sup>+</sup> and Ozonolysis of [(cyclam-acetato)Fe<sup>III</sup>(O<sub>3</sub>SCF<sub>3</sub>)]<sup>+</sup> in Water/Acetone Mixtures

Craig A. Grapperhaus, Bernd Mienert, Eckhard Bill et al. · Inorganic Chemistry · 2000 · 312 citations

, , +12

Structures of Nonheme Oxoiron(<scp>IV</scp>) Complexes from X‐ray Crystallography, NMR Spectroscopy, and DFT Calculations

Eric J. Klinker, József Kaizer, William W. Brennessel et al. · Angewandte Chemie International Edition · 2005 · 267 citations

, , +14

Formation, Structure, and EPR Detection of a High Spin Fe<sup>IV</sup>—Oxo Species Derived from Either an Fe<sup>III</sup>—Oxo or Fe<sup>III</sup>—OH Complex

David C. Lacy, Rupal Gupta, Kari L. Stone et al. · Journal of the American Chemical Society · 2010 · 252 citations

, , +16