Effect of rotational coupling on emission probabilities of Lyman and Werner band systems of the vacuum ultraviolet spectrum of H2

Abstract

Ratios of emission probabilities of rotational lines of the Lyman and Werner band systems, B 1∑+u →X 1∑+g and C 1∏u →X1∑+g, respectively, are calculated by different methods. These theoretical ratios are compared to the experimental intensity ratios of about a hundred lines selected from a vacuum ultraviolet emission spectrum whose intensity is investigated for the first time at high resolution. The computation permits to compare two ways of solving a system of two coupled equations with discrete eigenvalues. In most cases the effect of the mutual rotational perturbation between B and C states is found significant on the ratio of P and R line intensities. Ambiguity in labeling a few B and C levels is discussed.