Journal of Physics F Metal Physics · 1983 · 45 citations · 23 references
Natural SciencesMaterials EngineeringMaterials ScienceCondensed Matter PhysicsMaterials ThermodynamicsThermodynamicsAlloy ThermodynamicsAlloysMixing ThermodynamicsPhase DiagramsPhase EquilibriaThermodynamics Of Phase EquilibriaConcentrationConcentration DependenceLiquid Alloy ThermodynamicsMixing In Liquid AlloysSolid-solution ThermodynamicsSpecific Heat CapacitySpecific Heat DeterminationThermodynamic Analysis
The EMF of Na in the liquid Na-Pb system has been measured as a function of temperature using a concentration cell. The associated thermodynamic quantities of mixing Delta G, Delta S and Delta H are obtained, and the deviation from the additivity of specific heat, Delta Cp, is also obtained. The curve of the concentration-concentration fluctuation in the long-wavelength limit, SCC(0), obtained from Delta G, shows three kinds of atomic associations at the compositions of Na4Pb, NaPb and NaPb, respectively.
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A theory of the electrical properties of liquid metals
T. E. Faber, John Ziman · Philosophical magazine · 1965 · 1.5K citations