Publication | Closed Access
Palladium-Catalyzed Asymmetric Alkylation of 2,3-Alkadienyl Phosphates. Synthesis of Optically Active 2-(2,3-Alkadienyl)malonates
102
Citations
27
References
2002
Year
Engineering2,3-Alkadienyl PhosphatesAbstract Asymmetric AlkylationOrganic ChemistryOptically ActiveOrganometallic CatalysisCatalysisPalladium-catalyzed Asymmetric AlkylationChemistryAsymmetric CatalysisSynthetic ChemistryEnantioselective SynthesisBiomolecular EngineeringPalladium Complex Catalyst
Abstract Asymmetric alkylation of 2,3-alkadienyl phosphates with soft carbon nucleophiles proceeds efficiently in the presence of palladium complex catalyst bearing MeOBIPHEP or BINAP ligand to give optically active functionalized allenes up to 90% ee.
| Year | Citations | |
|---|---|---|
Page 1
Page 1