Concepedia

Luminescence vapochromic properties of a platinum(ii) complex with 5,5′-bis(trimethylsilylethynyl)-2,2′-bipyridine

Jun Ni, Li-Yi Zhang, Huimin Wen, Zhong-Ning Chen

Chemical Communications · 2009 · 85 citations · 32 references

DOI

Concepts

Abstract

A platinum(II) complex of 5,5'-bis(trimethylsilylethynyl)-2,2'-bipyridine displays unusually reversible colour and luminescence changes when exposed to specific organic vapours, correlated well with Pt...Pt distances as well as pi-pi and C-H...(C[triple bond]C) interactions in the stacking of square-planar platinum(II) moieties.

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