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The first compound with a stable xenon-carbon bond: 19F- and 129Xe-n.m.r. spectroscopic evidence for pentafluorophenylxenon(II) fluoroborates
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1989
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Inorganic ChemistryChemical EngineeringEngineeringPhysicsNovel CationsSpectroscopic EvidenceNatural SciencesFluorous SynthesisOrganic ChemistryChemistryStable Xenon-carbon BondMolecule-based MaterialInorganic SynthesisXenon DifluorideFirst Compound
Pentafluorophenylxenon(II) fluoroborates have been synthesized by the reaction of xenon difluoride with tris(pentafluorophenyl)borane and characterized by 129Xe- and 19F-n.m.r. spectroscopy and by reaction with bis(pentafluophenyl)tellurium and pentafluorophenliodine to yield the novel cations [(C6F5)3Te]+ and [(C6F5)2l]+, respectively