Macromolecular Rapid Communications · 2003 · 20 citations · 24 references
Natural SciencesMaterials EngineeringMaterials SciencePolymer ChemistryPolymer EngineeringPolymer MaterialsComposite MaterialsNanocompositesPolymer CharacterizationPolymer CompositesPolymer NanocompositesPolymeric NanomaterialsClay NanocompositesElectrical PropertiesMicrostructural AlterationNanocomposite MaterialsNanocomposite PolymersNanocomposite ProcessingPolymeric NanocompositesRheological Properties
Abstract A novel approach to fabricate poly(propylene)/clay nanocomposites under an electric field without adding any compatibilizer was proposed. The electrically activated poly(propylene)/clay nanocomposites show enhanced rheological properties with the disappearance of the characteristic peak in X‐ray diffraction. Transmission electron microscopy was used to confirm the microstructural changes of the nanocomposites. Electric field was found to facilitate destruction of the layer‐stacking and separation of the silicate layers. Time sweep results of poly(propylene)/clay composites before and after applying an electric field at 180 °C. magnified image Time sweep results of poly(propylene)/clay composites before and after applying an electric field at 180 °C.
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Polymer Layered Silicate Nanocomposites
Emmanuel P. Giannelis · Advanced Materials · 1996 · 3.5K citations
Natural Sciences, Materials Engineering, Materials Science +17