Concepedia

First successful enantiomeric discrimination of chiral alkanes using NMR spectroscopy

Muriel Sarfati, Jacques Courtieu, Philippe Lesot

Chemical Communications · 2000 · 57 citations · 5 references

DOI

Concepts

Abstract

Natural abundance deuterium NMR spectroscopy in a chiral polypeptide liquid crystal solvent (PBLG) is used to successfully discriminate between chiral alkanes.

References

5

Two-Dimensional Deuterium NMR Spectroscopy of Chiral Molecules Oriented in a Polypeptide Liquid Crystal: Applications for the Enantiomeric Analysis through Natural Abundance Deuterium NMR

Denis Merlet, Bernard Ancian, Jacques Courtieu et al. · Journal of the American Chemical Society · 1999 · 104 citations

, , +14

Polypeptide Liquid Crystals: A Deuterium NMR Study

K. Czarniecka, Edward T. Samulski · Molecular crystals and liquid crystals · 1981 · 100 citations

, , +15

Calculation of the Molecular Ordering Parameters of (±)-3-Butyn-2-ol Dissolved in an Organic Solution of Poly(γ-benzyl-<scp>l</scp>-glutamate)

Philippe Lesot, Denis Merlet, Jacques Courtieu et al. · The Journal of Physical Chemistry A · 1997 · 77 citations

, , +16

Visualization of enantiomers in a polypeptide liquid-crystal solvent through carbon-13 NMR spectroscopy

Philippe Lesot, Denis Merlet, Abdelkrim Meddour et al. · Journal of the Chemical Society Faraday Transactions · 1995 · 60 citations

, , +9

Deuterium NMR stereochemical analysis of threo–erythro isomers bearing remote stereogenic centres in racemic and non-racemic liquid crystalline solvents

Cécile Canlet, Denis Merlet, Philippe Lesot et al. · Tetrahedron Asymmetry · 2000 · 54 citations

, , +9