Analytical Chemistry · 2013 · 46 citations · 21 references
EngineeringMaterials EngineeringMaterials ScienceOptical MaterialsPhotonicsSensorsInfrared DetectorsInfrared SpectroscopyOptical DetectorsOptical SensingOptical SensorsSensor MaterialsFinite Difference Time Domain ModelingFinite Difference Time Domain SimulationMercury Cadmium TellurideMercury Cadmium Telluride DetectorsMolecular Beam EpitaxyPlanar Optical WaveguidesPlanar WaveguidesQuantum Cascade Lasers
We report the first planar waveguides made from mercury-cadmium-telluride (MCT)-a material to date exclusively used for mid-infrared (MIR) detector elements-serving as on-chip MIR evanescent field transducers in combination with tunable quantum cascade lasers (tQCLs) emitting in the spectral regime of 5.78-6.35 μm. This novel MIR sensing approach utilizes structured MCT chips fabricated via molecular beam epitaxy (MBE) as waveguide enabling sensing via evanescent field absorption spectroscopy, as demonstrated by the detection of 1 nL of acetone. Complementary finite difference time domain (FDTD) simulations fit well with the experimentally obtained data and predict an improvement of the limit of detection by at least 2 orders of magnitude upon implementation of thinner MCT waveguides. With the first demonstration of chemical sensing using on-chip MCT waveguides, monolithically fabricated IR sensing systems directly interfacing the waveguide with the MCT detector element may be envisaged.
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