Synthesis and optical properties of well-aligned ZnO nanorod array on an undoped ZnO film

Abstract

High-density well-aligned ZnO nanorod array was successfully synthesized on a PLD prepared undoped ZnO film by a catalyst-free method. X-ray diffraction and scanning electron microscopy show that the nanorods are well-oriented perpendicular to the substrate. The photoluminescence from free excitons and Raman spectra of the ZnO nanorods reflect the high purity and nearly defect free structure of nanorods. The well-aligned feature of the nanorod array is attributed to the nanorods’ epitaxial growth from the ZnO film.