Synthesis, structure and complexes of a new bicyclic N,P-ligand derived from phosphatriazaadamantane

Bernd Assmann, Klaus Angermaier, Hubert Schmidbaur

Journal of the Chemical Society Chemical Communications · 1994 · 26 citations · 5 references

Concepts

Abstract

Reductive cleavage of the methylphosphoniatriazaadamantane cation by sodium in liquid ammonia affords the new bicyclic ligand (MeP)(CH2)5N2(NMe) whose structure has been determined from crystals of its 1 : 1 complex with AuCl.

References

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