An End‐On Azide‐Bridged Antiferromagnetic Single‐Chain Magnet Involving Spin Canting and Field‐Induced Two‐Step Magnetic Transitions

Abstract

Two-step magnetic transitions: An azide-bridged 1D Mn(III) coordination polymer with a unique single end-on mode was prepared; it displayed atypical antiferromagnetic couplings and field-induced two-step magnetic transitions (see figure). The spin-canted phenomenon in the antiferromagnetic chain complex plays a pivotal role in establishing the slow magnetic relaxation.