An End‐On Azide‐Bridged Antiferromagnetic Single‐Chain Magnet Involving Spin Canting and Field‐Induced Two‐Step Magnetic Transitions

Jung Hee Yoon, Dae Won Ryu, Hyoung Chan Kim, Sung Won Yoon, Byoung Jin Suh, Chang Seop Hong

Chemistry - A European Journal · 2009 · 103 citations · 61 references

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Abstract

Two-step magnetic transitions: An azide-bridged 1D Mn(III) coordination polymer with a unique single end-on mode was prepared; it displayed atypical antiferromagnetic couplings and field-induced two-step magnetic transitions (see figure). The spin-canted phenomenon in the antiferromagnetic chain complex plays a pivotal role in establishing the slow magnetic relaxation.

References

61