Concepedia

Electrochemistry of 1,1,2,2,3,3-hexa(2,6-diethylphenyl)cyclotristannane. The first examples of electrochemical generation of a stannylene radical anion and a tristannane radical cation

Ivan Orlov, Anna A. Moiseeva, K. P. Butin, Lawrence R. Sita, Mikhail P. Egorov

Mendeleev Communications · 2002 · 10 citations · 7 references

DOI

Concepts

Abstract

The radical anion of di(2,6-diethylphenyl)stannylene (Ar2Sn) has been generated by the electrochemical reduction of cyclotristannane cyclo-(Ar2Sn)3, and the electrochemical oxidation of cyclo-(Ar2Sn)3 resulted in Sn–Sn bond cleavage with the formation of the radical cation of tristannane.

References

7

Strained‐Ring and Double‐Bond Systems Consisting of the Group 14 Elements Si, Ge, and Sn

Takeshi Tsumuraya, Scott A. Batcheller, Satoru Masamune · Angewandte Chemie International Edition in English · 1991 · 344 citations

, , +9

2,2,4,4,5,5-Hexakis(2,6-diethylphenyl)pentastanna[1.1.1]propellane: characterization and molecular structure

Lawrence R. Sita, Richard D. Bickerstaff · Journal of the American Chemical Society · 1989 · 153 citations

, , +6

A room temperature synthesis of perstanna[1.1.1]propellanes and the structure/property relationships revealed by a comparison of two derivatives

Lawrence R. Sita, Isamu Kinoshita · Journal of the American Chemical Society · 1992 · 67 citations

, , +10

Molecular structures and reactivities of digermiranes and azadigermiridines

Takeshi Tsumuraya, Sadao Sato, Wataru Andō · Organometallics · 1990 · 59 citations

, , +8

Sensitised (electron-transfer) photochemical reactions of cyclopolysilanes, (R<sup>1</sup>R<sup>2</sup>Si)<sub>n</sub>(n= 3 or 4), in a polar, nucleophilic solvent; electron donating nature of cyclopolysilanes (n= 3–7)

Hamao Watanabe, Motohiko Kato, Eiichi Tabei et al. · Journal of the Chemical Society Chemical Communications · 1986 · 26 citations

, , +14