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A hyperspherical close-coupling calculation of photoionization from the He atom, Li<sup>+</sup>and C<sup>4+</sup>ions. I. Below the N=2 threshold
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Citations
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References
1993
Year
EngineeringNuclear PhysicsProton-coupled Electron TransferN=2 ThresholdComputational ChemistryChemistryElectronic Excited StateVibronic InteractionElectron SpectroscopyQuantum SciencePhotoionization Cross SectionsHyperspherical Close-coupling CalculationPhysicsPhotochemistryAtomic PhysicsQuantum ChemistrySynchrotron RadiationInner ElectronExcited State PropertyNatural SciencesSpectroscopyApplied PhysicsDeveloped Hyperspherical Close-coupling
The authors give a detailed account of the formulation of the recently developed hyperspherical close-coupling (HSCC) method. Using this method, they have made calculations of photoionization cross sections for the He atom and He-like ions, Li+ and C4+ below the N=2 (the inner electron's principal quantum number) threshold. From analysing the photoionization cross section spectra and resonance structures of the two-electron systems with different nuclear charge, the effect of the interplay between the electron-nucleus and electron-electron interactions on doubly excited states is studied.
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