Efficient oxidation of alcohols with tert-butyl hydroperoxide catalyzed by Mo(CO)6 supported on multiwall carbon nanotubes

Abstract

Efficient oxidation of alcohols with tert -butyl hydroperoxide catalyzed by Mo(CO) 6 supported on multiwall carbon nanotubes modified with 4-aminopyridine is reported. The effect of various parameters such as catalyst amount, solvent and oxidant was studied. The catalyst, [Mo(CO) 5 @APy-MWCNT], showed high activity not only in the oxidation of benzylic and linear alcohols but also in the oxidation of secondary alcohols. The catalyst can be reused several times without significant loss of its activity.