TRENDS IN THE SCIENCES · 2009 · 798 citations · 0 references
Natural SciencesChemical EngineeringChemistryCatalysisGreen ChemistryOrganic ChemistryChemical OxidationOxidation ReactionsOxidation-reduction ReactionsRedox ChemistryRedox ProcessesRedox ReactionsGreen Oxidation ChemistryGreen Oxidation ProcessesHydrogen Peroxide ChemistryHydrogen Sulfide OxidationOxidationPhase-transfer CatalysisQuaternary Ammonium Compounds
Aqueous H202 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogen sulphate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in aneconomically, technically and environmentally satisfying manner.