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Green Oxidation with Aqueous Hydrogen Peroxide
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2009
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Advanced Oxidation ProcessChemical EngineeringEngineeringOxidation ResistanceAdvanced Oxidation ProcessesGreen ChemistryAcidic Phase-transfer CatalystOrganic ChemistryGreen OxidationTungstate ComplexCatalysisRedox ChemistryChemistryHydrogenHomogeneous CatalysisRedox BiologyDeoxygenationAqueous H202
Aqueous H202 is an ideal oxidant, when coupled with a tungstate complex and a quaternary ammonium hydrogen sulphate as an acidic phase-transfer catalyst. It oxidizes alcohols, olefins, and sulfides under organic solvent- and halide-free conditions in aneconomically, technically and environmentally satisfying manner.