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Some Novel Eliminations of Neutral Fragments from Ions in Mass Spectrometry
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1966
Year
C LabellingRadical EmissionBiological Mass SpectrometryStilbene IonsOrganic ChemistryIon Mobility SpectrometryChemistryMethyl RadicalsSpectrochemical AnalysisIon ProcessAnalytical ChemistryNovel EliminationsChromatographyBiochemistryRadical (Chemistry)Neutral FragmentsMetabolomicsPharmacologyIon MobilityNatural SciencesMass SpectrometryMedicineMolecular Fragmentation
The loss of methyl radicals from diphenylmethyl, 1,2-diphenylethyl and stilbene ions in the mass spectrometer has been studied by means of 2 H and 13 C labelling. Mechanisms by which these methyl radicals are eliminated have been proposed.