Temperature dependence of lattice parameters and spontaneous strain in Pb<sub>3</sub>(PO<sub>4</sub>)<sub>2</sub>

D. M. C. Guimaraes

Phase Transitions · 1979 · 23 citations · 10 references

Concepts

Abstract

Abstract Precise measurements of the lattice parameters of Pb3(PO4)2 as a function of temperature are presented, from which the spontaneous strain and its tensor components are calculated. The ferroelastic transition is shown to be of first order. Mean-field theory is shown to describe the experimental behaviour of the material, with a crossover, at about 160°C, from a critical to a first-order regime. This result is interpreted on the basis of the temperature dependence of elastic constant c22.

References

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