Journal of Physics C Solid State Physics · 1978 · 104 citations · 18 references
Natural SciencesMaterials EngineeringMaterials ScienceCeramic MaterialsCeramicsSolid State PhysicsCrystalline MaterialsDielectricsElectrical Properties Of CeramicsFerroelectric MaterialsPhase TransitionsSolid-state Phase TransitionsDielectric ConstantDielectric Constant MeasurementFerroelectric Phase TransitionsFerroelectric PropertiesFerroelectric Single CrystalsPhase Transitions In Dielectric CeramicsPiezoelectricityTricritical Point
Evidence is presented for the existence of a tricritical point at the ferroelectric-paraelectric transition of PbZrxTi1-xO3 close to a value of x=0.94. Details are given of measurements of dielectric constant, remanent polarisation and spontaneous strain. It is also observed that in single crystals of PbZrxTi1-xO3 there is a peak in the transition temperature versus composition diagram coinciding with the tricritical composition. This is not seen in ceramics of the same composition.
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