Advanced Materials · 2012 · 812 citations · 40 references
Natural SciencesMaterials EngineeringMaterials ScienceBiomedical OpticsElectronic MaterialsOptical MaterialsLuminescent MaterialsMetal OxidesOxide SemiconductorsRare-earth-doped MaterialsUpconversion MaterialsCo-dopingIn Vivo ImagingLuminescence LifetimeOxide DopingRare-earth OxidesTemperature SensingTemperature-dependent Upconversion EmissionUpconversion Luminescence
A novel high excited state energy transfer pathway to overcome the phonon quenching effect in rare-earth (RE) oxide upconversion (UC) materials is reported. In Er(Tm)-Yb oxide systems, an extraordinary enhancement of UC luminescence efficiency with four orders of magnitude is realized by Mo co-doping. The RE oxides with significant UC efficiency are successfully utilized for temperature sensing and in vivo imaging.
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