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Gewinnung von 1;4‐Bisdehydro‐3‐oxo‐steroiden. Über Steroide, 139. Mitteilung
81
Citations
18
References
1956
Year
EngineeringüBer SteroideOrganic ChemistryChemistryBiosynthesisAlcohol DehydrogenasesSteroid MetabolismAldehyde DehydrogenaseOxysterolBiochemistryDiversity-oriented SynthesisNatural Product SynthesisPharmacologyTertiary AlcoholBiomolecular EngineeringSelenium DioxideChemical StepNatural SciencesSynthetic Chemistry
Abstract A method is described which enables the production in only one chemical step of 1,4‐bisdehydro‐3‐oxo‐steroids inter alia from 3‐oxo‐ steroids saturated in ring A or from the α β‐mono‐unsaturated 3‐ketones. The dehydrogenating agent is selenium dioxide and the solvent a tertiary alcohol preferably containing some acid.
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