Concepedia

Synthesis and Structure of the First Transition Metal Borylene Complexes

Holger Braunschweig, Trixie Wagner

Angewandte Chemie International Edition in English · 1995 · 140 citations · 7 references

DOI

Concepts

Abstract

The stable borylene-bridged Mn2 complexes 1 and 2 are formed in the reaction of K[(η5-C5H4R)-Mn(SiMePh2)(CO)2] with the diboranes(4) B2X2Cl2. The mechanism of formation still remains to be clarified. The molecular structure of 1 (R = H) shows similarities with dimetallacyclopropane derivatives.

References

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Stabilization of Diborane(4) Derivatives by <i>tert</i>‐Butyl Groups: The First Tetraalkyldiborane(4)

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