Stereogenic Motif Consisting of Rigid Ring and Intraannular Chains: Isolation and Structures of Stereoisomers of 9-Alkyl-1,8-anthrylene−Butadiynylene Cyclic Dimers

Abstract

Stereoisomers of the title pi-conjugated compounds with intraannular propyl and butyl groups were isolated by chromatography. The high barrier to isomerization is attributed to the steric hindrance between the alkyl chains and the rigid framework.