Zirconoxycarbene complexes obtained by regioselective coupling of (isoprene)zirconocene with hexacarbonyltungsten and a ketone. Crystal structure of Cp2H2

Synthesis, structure, and equilibration of s-cis- and s-trans- .eta.4-conjugated diene-zirconocene complexes

Gerhard Erker, Joachim Wicher, Klaus Engel et al. · Journal of the American Chemical Society · 1980 · 220 citations

Natural Sciences, Chemistry, Inorganic Chemistry +10

Metallacyclopentanes and bisolefin complexes

Armel Stockis, Roald Hoffmann · Journal of the American Chemical Society · 1980 · 192 citations

Natural Sciences, Chemistry, Analytical Chemistry +7

1,3-Diene complexes of zirconium and hafnium prepared by the reaction of enediylmagnesium with MCl2Cp2. A remarkable difference between the zirconium and hafnium analogs as revealed by proton NMR and electronic spectra

Hajime Yasuda, Yasuhiro Kajihara, Kazushi Mashima et al. · Organometallics · 1982 · 162 citations

Natural Sciences, Chemistry, Inorganic Chemistry +11

Reduction of coordinated carbon monoxide to "zirconoxy" carbenes with permethylzirconocene dihydride

Peter T. Wolczanski, Richard S. Threlkel, John E. Bercaw · Journal of the American Chemical Society · 1979 · 112 citations

Natural Sciences, Chemistry, Catalysis +5

Migratory insertion reactions of carbenes. Kinetics and mechanism of migratory insertion reactions of zirconoxy carbene complexes of niobocene hydride and alkyls

Richard S. Threlkel, John E. Bercaw · Journal of the American Chemical Society · 1981 · 93 citations

Natural Sciences, Chemistry, Chemical Kinetics +12