Concepedia

A mixed-valence copper coordination polymer generated by hydrothermal metal/ligand redox reactionsElectronic supplementary (ESI) available: the effective molar magnetic moment µeff of 1 vs. T. See http://www.rsc.org/suppdata/cc/b2/b203301a/

Jun Tao, Yong Zhang, Ming‐Liang Tong, Xiao‐Ming Chen, Tan Yuen, Ching‐Long Lin, Xiao‐Ying Huang, Jing Li

Chemical Communications · 2002 · 241 citations · 15 references

DOI

Concepts

Abstract

A novel coordination polymer of mixed-valence copper(I,II) with 4,4'-bipyridine and in situ oxidized isophthalate, [Cu2(ipO)(4,4'-bpy)] (ipOH = 2-hydroxyisophthalate), was hydrothermally synthesized and crystallographically characterized to be a laminated structure via weak copper(II)--oxygen interactions.

References

15

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