The effect of light rare earth element substitution in Yb<sub>14</sub>MnSb<sub>11</sub>on thermoelectric properties

Yufei Hu, Sabah K. Bux, Jason H. Grebenkemper, Susan M. Kauzlarich

Journal of Materials Chemistry C · 2015 · 42 citations · 40 references

Concepts

Abstract

The<italic>zT</italic>of Yb<sub>14</sub>MnSb<sub>11</sub>is improved by the introduction of a light rare earth element, RE<sup>3+</sup>(RE = Pr, Sm) with partially filled f-levels. The carrier concentration is reduced upon substituting RE<sup>3+</sup>for Yb<sup>2+</sup>, adding one electron to the system and improving the<italic>zT</italic>values 30–40% over that of the pristine material.

References

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