International Journal of Polymer Analysis and Characterization · 2015 · 31 citations · 20 references
Natural SciencesMaterials EngineeringMaterials SciencePolymer ChemistryPolymer EngineeringPolymer MaterialsAcrylic Resin MaterialsCoating TechnologyCoatingsGreen Polymer ChemistryThermosetsAcrylic CoatingsGreen Polyurethane ChemistryMonomer SynthesisPolymer-based CoatingsPolyurethane MaterialsRenewable MonomersThermal PropertiesUltraviolet-resistant Materials
A series of novel waterborne UV-curable polyurethane dispersions were synthesized from castor oil, IPDI, DMPA, and HEMA by the acetone process. The prepared UV-PUD was mixed with three different monomers and characterized for the parameters relevant to the study by physical, spectroscopic, and chemical methods. The effect of monomer type on the physicochemical and thermal properties of UV-PUDs revealed that the number of unsaturated groups present in the monomer had a pronounced effect on physicochemical, mechanical, and thermal properties. The combination of renewable resource and environmentally compliant technology give these UV-PUDs potential scope in coating applications.
20