Small Gold Nanoparticles as Crystallization “Catalysts”: Effect of Seed Size and Concentration on Au-ZnO Hetero Nanoparticles

Abstract

This work reports the effect of seed nanoparticle size and concentration effects on heterogeneous crystal nucleation and growth in colloidal suspensions. We examined these effects in the Au nanoparticle-seeded growth of Au-ZnO heteronanocrystals under synthesis conditions that generate hexagonal, cone-shaped ZnO nanocrystals. It was observed that small (∼4 nm) Au seed nanoparticles form one-to-one Au-ZnO hetero dimers and that Au nanoparticle seeds of this size can also act as crystallization “catalysts” that readily promote the nucleation and growth of ZnO nanocrystals. Larger seed nanoparticles (∼9 and ∼11 nm) provided multiple, stable ZnO-nucleation sites, generating multicrystalline hetero trimers, tetramers, and oligomers.