Interface dipole between two metallic oxides caused by localized oxygen vacancies

Abstract

Oxygen vacancies are increasingly recognized to play a role in phenomena observed at transition-metal oxide interfaces. Here, we report a study of SrRuO${}_{3}$ and La${}_{0.7}$Sr${}_{0.3}$MnO${}_{3}$ interfaces using a combination of quantitative aberration-corrected scanning transmission electron microscopy, electron energy-loss spectroscopy, and density functional calculations. Cation displacements are observed at the interface, indicative of a dipolelike electric field even though both materials are nominally metallic. The observed displacements are reproduced by theory if O vacancies are present in the near-interface La${}_{0.7}$Sr${}_{0.3}$MnO${}_{3}$ layers. The results suggest that atomic-scale structural mapping can serve as a quantitative indicator of the presence of O vacancies at interfaces.