Bulletin of the American Astronomical Society · 1984 · 26 citations · 0 references
Natural SciencesAstronomyChemistryInfrared AstronomyInterstellar MediumSpectroscopyAtmospheric IonizationCircumstellar ChemistryInterstellar MoleculesCircumstellar Envelope ChemistryCosmic Ray ChemistryCosmic-ray IonizationDissociative RecombinationIonization StructureMass Loss KineticsPhotoionization KineticsPhotoionization Processes
Assuming a steady and spherically symmetric mass loss, the spatial distribution of the ionization in a C-rich circumstellar envelope (CSE) is calculated, and it is shown that molecular ions dominate the ionization and chemistry of a large part of the CSE. Cosmic ray ionization of molecular hydrogen yields H3(+), and the photoionization of acetylene and neutral carbon yields C2H2(+) and C(+). In the system, the primary ions generate a series of heavier molecular ions by reactions with neutral molecules before being destroyed by dissociative recombination. The most promising candidate for mm-wavelength detection is found to be HCO(+), and IRC + 10216 antenna temperatures are calculated for different telescope sizes. Photoproduced C2H2(+), the most abundant intermediate distance CSE ion, may be responsible for the synthesis of various heavy hydrocarbon molecules at levels observed in IRC + 10216.