Journal of the Physical Society of Japan · 1961 · 78 citations · 6 references
Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistrySolid-state ChemistryCrystal ChemistryCrystal SymmetryCrystallographyStructure DeterminationX-ray CrystallographyX-ray DiffractionAtomic BondingCrystal Structure DeterminationCrystal Structure RefinementCrystal Symmetry DeterminationSingle-crystal X-ray DiffractionUnit Cell DeterminationUnit Cell GeometryUnit Cell Parameters
The crystal structure of NiCl 2 ·6H 2 O has been determined by the X-ray single crystal method. The unit cell is monoclinic with a =10.23 Å, b =7.05 Å, c =6.57 Å and β=122°10'. The space group is C 2 h 3 – C 2/ m and the unit cell contains two formula units. The atomic arrangement is quite the same as that of CoCl 2 ·6H 2 O and thus the structure model adopted for this salt has again been confirmed to be correct, as compared with the model proposed by Stroganov et al. .
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