Cooperative downconversion in GdAl3(BO3)4:RE3+,Yb3+ (RE=Pr, Tb, and Tm)

Abstract

An efficient near-infrared (NIR) quantum cutting (QC) in GdAl3(BO3)4:RE3+,Yb3+ (RE=Pr, Tb, and Tm) phosphors has been demonstrated, which involves the conversion of the visible photon into the NIR emission with an optimal quantum efficiency approaching 200%, by exploring the cooperative downconversion mechanism from RE3+ (RE=Pr, Tb, and Tm) excitons to the two activator ions, Yb3+. The development of NIR QC phosphors could open up a new approach in achieving high efficiency silicon-based solar cells by means of downconversion in the visible part of the solar spectrum to ∼1000nm photons with a twofold increase in the photon number.