Effect of BF3 on the enantioselective reduction of trifluoromethyl ketones using a chiral lactam alcohol with borane

Highly enantioselective borane reduction of ketones catalyzed by chiral oxazaborolidines. Mechanism and synthetic implications

E. J. Corey, Raman K. Bakshi, Saizo Shibata · Journal of the American Chemical Society · 1987 · 1.4K citations

Natural Sciences, Chemistry, Biocatalysis +10

Fluorine chemistry at the millennium

William R. Dolbier · Journal of Fluorine Chemistry · 2004 · 398 citations

Natural Sciences, Chemistry, Medicinal Chemistry +6

A mechanistic and structural analysis of the basis for high enantioselectivity in the oxazaborolidine-catalyzed reduction of trihalomethyl ketones by catecholborane

E. J. Corey, John O. Link, Raman K. Bakshi · Tetrahedron Letters · 1992 · 78 citations

Natural Sciences, Chemistry, Biocatalysis +16

Nonenzymatic kinetic resolution of racemic 2,2,2-trifluoro-1-aryl ethanol via enantioselective acylation

Qing Xu, Hui Zhou, Xiaohong Geng et al. · Tetrahedron · 2009 · 71 citations

Natural Sciences, Chemistry, Catalysis +10

Remarkably effective and simple syntheses of enantiomerically pure secondary carbinols from achiral ketones

E. J. Corey, Xue‐Min Cheng, Karlene A. Cimprich et al. · Tetrahedron Letters · 1991 · 61 citations

Natural Sciences, Chemistry, Medicinal Chemistry +7