Synthesis of : Sugar moiety of antitumor antibiotic bleomycin

The Use of Diethyl Azodicarboxylate and Triphenylphosphine in Synthesis and Transformation of Natural Products

Oyo Mitsunobu · Synthesis · 1981 · 4.1K citations

Natural Sciences, Biochemistry, Chemistry +8

Facile Synthesis of α‐ and β‐<i>O</i>‐Glycosyl Imidates; Preparation of Glycosides and Disaccharides

Richard R. Schmidt, Josef Michel · Angewandte Chemie International Edition in English · 1980 · 815 citations

Pharmacy, Biochemistry, Carbohydrate Biochemistry +6

New antibiotics, bleomycin A and B.

Hitoshi Umezawa, Kazuhiko Maeda, Tsutomu Takeuchi et al. · PubMed · 1966 · 732 citations

Pharmacy, Pharmacology, Pharmacotherapy +9

On the selectivity of deprotection of benzyl, mpm (4-methoxybenzyl) and dmpm (3,4-dimethoxybenzyl) protecting groups for hydroxy functions

Kiyoshi Horita, Tadao Yoshioka, Tatsuyoshi Tanaka et al. · Tetrahedron · 1986 · 509 citations

Pharmacy, Chemistry, Medicinal Chemistry +5

Lithium tri-sec-butylborohydride. New reagent for the reduction of cyclic and bicyclic ketones with super stereoselectivity. Remarkably simple and practical procedure for the conversion of ketones to alcohols in exceptionally high stereochemical purity

Herbert C. Brown, S. Krishnamurthy · Journal of the American Chemical Society · 1972 · 292 citations

Natural Sciences, Chemistry, Analytical Chemistry +7