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Rhodium-catalyzed Direct Coupling of Benzothioamides with Alkenes and Alkynes through Directed C–H Bond Cleavage
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Citations
31
References
2015
Year
Chemical EngineeringRhodium-catalyzed Direct CouplingDerivativesEngineeringAlkene MetathesisCross-coupling ReactionOrtho-c–h Bond CleavageIndenone DerivativesOrganic ChemistryOrganometallic CatalysisCatalysisMolecular CatalysisChemistryC–n Bond CleavageBiomolecular Engineering
Abstract Rhodium-catalyzed direct coupling of benzothioamides with alkenes proceeds smoothly involving ortho-C–H bond cleavage. The thioamides also couple with alkynes under similar conditions accompanied by desulfurization and C–N bond cleavage to produce indenone derivatives.
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