Concepedia

STEREOCHEMISTRY OF COMPLEXES OF MULTIDENTATE LIGANDS

Moo-Jin Jun, Chui Fan Liu

Journal of Coordination Chemistry · 1975 · 10 citations · 16 references

DOI

Concepts

Abstract

Abstract Dichloro, dinitro, and diacetato cobalt(III) complexes of a new tetramine ligand, 1,7-bis(2-S-pyrrolidyl)-2,6-diazaheptane (SS-pyht) have been prepared and characterized. Only the trans isomer has been obtained for each complex. Oxalate ion reacts with trans-[Co(SS-pyht)Cl2]ClO4 in aqueous media to produce A-cis-β-[Co(SS-pyht)Ox]ClO4.

References

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