On the Absorption Spectra of Hexamminecobalt (III) and Related Complexes. II. Theoretical Study on Shifting and Spilitting of the First and the Second Band Due to Substitution of Ligands

Abstract

Abstract A general theory has been presented to discussed spectra of transition metal complexes and to apply them to the problem of shifting and spliting of the absorption band of the cobalt (III) complex due to replacement of some of the ligends. The problem was discussed from the molecularorbital and the electrosttaic point of view.