On the structure of the mesomorphic form of syndiotactic polystyrene

Abstract

Abstract In this contribution, the X‐ray diffraction (XRD) pattern of a highly oriented sample of syndiotactic polystyrene in the mesomorphic form, collected by an automatic diffractometer, is presented, thus providing quantitative and more complete information relative to the diffracted intensity. The structural changes induced by annealing procedures in mesomorphic samples are shown through the analysis of the XRD patterns: both unoriented and oriented mesomorphic samples are transformed gradually into α‐form crystals. On the basis of these evidences and of preliminary comparisons between the calculated Fourier transform of simplified models and the experimental diffraction intensity, it is suggested that the local organization in triplets of trans ‐planar chains, typical of the different modifications of the α‐form, would be largely present also in the disordered chain agglomerates of the mesomorphic form.