Quarterly of Applied Mathematics · 1988 · 80 citations · 16 references
Natural SciencesPhysicsCondensed Matter PhysicsFluid DynamicsThermodynamicsFree EnergyPhase EquilibriaPhase TransitionsSurface EnergyThermodynamics Of Phase EquilibriaCahn-hilliard EquationCahn-hilliard ModelingCahn-hilliard TheoryDensityEquilibrium TransitionsGradient Energy Theory
1. Introduction. In the van der Waals/Cahn-Hilliard theory ([20], We shall consider this theory, but only with a relatively simple dependence on Vu, and only as restricted to isothermal situations; precisely, we shall allow for a free-energy (per unit volume) of the form
16
Free Energy of a Nonuniform System. I. Interfacial Free Energy
John W. Cahn, J. E. Hilliard · The Journal of Chemical Physics · 1958 · 10.3K citations
Natural Sciences, Chemistry, Physics +17
John W. Cahn · Acta Metallurgica · 1961 · 3.5K citations