Zeitschrift für Naturforschung A · 1972 · 82 citations · 3 references
EngineeringRadiation EffectRadiation ExposureOrganic ChemistryChemistryThermal RadiationRadiation GenerationOrganic Crystals IrradiatedVery Low TemperatureThermodynamicsRadiation ChemistryMaterials SciencePhysicsPhotochemistryPhysical ChemistryRadiation DamageRadiation ApplicationRadiation EffectsPhotodegradationNatural SciencesApplied PhysicsLow-temperature PhysicsSecondary Radiation DamagePrimary Radiation DamageChemical Kinetics
Abstract The radiation damage of electron irradiated organic compounds (paraffin, tetracene) was investigated in the temperature range 300 - 4 K. The radiation damage was measured by the decrease of diffraction intensities or the contrast of extinction contours. The damage of the crystals at 4 K required considerable higher electron doses than at 300 K. This result is explained as follows: The total radiation damage proceeds by two steps: 1) By primary radiation damage - excitation of energy levels with subsequent dissociation - which is almost temperature independent, 2) by secondary radiation damage - diffusion of molecular fragments - which decreases strongly with decreasing temperature.
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