Concepedia

Stepwise Reductive Elimination

Stepwise Reductive Elimination is a mechanistic pathway in organometallic chemistry whereby a metal center undergoes sequential bond cleavage and electron reduction to eliminate two ligands as a coupled product, distinguished from concerted reductive elimination by the intermediacy of a discrete lower-valent metal species.

18

Publications

1.2K

Citations

79

Authors

29

Institutions

Publications per year

2017–2026

2

Parents

Publications

18

Direct conversion of mouse fibroblasts to self-renewing, tripotent neural precursor cells

Ernesto Lujan, Soham Chanda, Henrik Ahlenius et al. · Proceedings of the National Academy of Sciences · 2012 · 425 citations · Full text

, , +15

A novel type of Pt–C interaction and a model for the final stage in reductive elimination processes involving C–C coupling at Pt; synthesis and molecular geometry of [1,N,N′-η-2,6-bis{(dimethylamino)methyl}-toluene]iodoplatinum(<scp>II</scp>) tetrafluoroborate

Gerard van Koten, Klaas Timmer, J. G. NOLTES et al. · Journal of the Chemical Society Chemical Communications · 1978 · 192 citations

, , +17

Electrophilic Platinum Complexes:  Methyl Transfer Reactions and Catalytic Reductive Elimination of Ethane from a Tetramethylplatinum(IV) Complex

Geoffrey S. Hill, Glenn P. A. Yap, Richard J. Puddephatt · Organometallics · 1999 · 94 citations

, , +16

Mechanism of the reaction of trans-bis(diethylphenylphosphine)di-m-tolylpalladium(II) with methyl iodide affording m-xylene. Evidence for a reductive elimination process involving the intermolecular exchange of organic groups

Fumiyuki Ozawa, Mizue Fujimori, Takakazu Yamamoto et al. · Organometallics · 1986 · 81 citations

, , +9

Synthesis, Structure, and Reductive Elimination Reactions of the First (σ-Aryl)palladium Complex Stabilized by IPr N-Heterocyclic Carbene

William Marshall, Vladimir V. Grushin · Organometallics · 2003 · 78 citations

, , +12

1–5 of 18

Authors

79

  1. JC
    John C. Huffman

    Indiana University Bloomington, United States

    2 publications · 58 citations

    2

    h-index

  2. ZX
    Zheng‐Yang Xu

    University of Science and Technology of China, China

    1 publications · 40 citations

    1

    h-index

  3. DD
    Daniel D. Caspi

    AbbVie (United States), United States

    1 publications · 19 citations

    1

    h-index

  4. JW
    Joseph W. Bruno

    Wesleyan University, United States

    1 publications · 41 citations

    1

    h-index

  5. DL
    David L. Clark

    Los Alamos National Laboratory, United States

    1 publications · 17 citations

    1

    h-index

1–5 of 79

Institutions

29

  1. Victoria University of Wellington

    Wellington, New Zealand

    1 h-index

    1 publications

    15 citations

  2. State Key Laboratory of Synthetic Chemistry

    Hong Kong, China

    1 h-index

    3 publications

    30 citations

  3. Institute for Stem Cell Biology and Regenerative Medicine

    Bengaluru, India

    1 h-index

    4 publications

    1.7K citations

  4. Polish Academy of Sciences

    Warsaw, Poland

    1 h-index

    6 publications

    204 citations

  5. TU Wien

    Vienna, Austria

    1 h-index

    3 publications

    51 citations

  6. Zhejiang University

    Hangzhou, China

    1 h-index

    6 publications

    240 citations

  7. Yonsei University

    Seoul, South Korea

    1 h-index

    3 publications

    69 citations

  8. Columbia University

    New York, United States

    1 h-index

    9 publications

    198 citations

1–8 of 29

Venues

  1. Organometallics

    6 publications · 324 citations

    6

    h-index

  2. Journal of the American Chemical Society

    JACS · 3 publications · 97 citations

    3

    h-index

  3. Organic Letters

    OL · 2 publications · 51 citations

    2

    h-index

  4. Angewandte Chemie International Edition

    2 publications · 59 citations

    2

    h-index

  5. New Journal of Chemistry

    NJC · 1 publications · 17 citations

    1

    h-index

1–5