Concepedia

Reductive Elimination Competition

Reductive Elimination Competition is a reaction pathway in organometallic chemistry where the formation of a new covalent bond via reductive elimination competes kinetically and mechanistically with alternative processes, particularly migratory insertion, within the same metal-centered complex.

39

Publications

3.4K

Citations

132

Authors

52

Institutions

Publications per year

2017–2026

7

Parents

Publications

39

Pathways and Kinetics of Chlorinated Ethylene and Chlorinated Acetylene Reaction with Fe(0) Particles

William A. Arnold, A. Lynn Roberts · Environmental Science & Technology · 2000 · 687 citations

, , +15

Reactivity of Pd(II) Complexes with Electrophilic Chlorinating Reagents:  Isolation of Pd(IV) Products and Observation of C−Cl Bond-Forming Reductive Elimination

Salena R. Whitfield, Melanie S. Sanford · Journal of the American Chemical Society · 2007 · 355 citations

, , +13

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C<sub>2</sub>N<sub>2</sub>O<sub>2</sub>−Ligated Palladium(IV) Complexes

Joy M. Racowski, Allison R. Dick, Melanie S. Sanford · Journal of the American Chemical Society · 2009 · 343 citations

, , +16

Oxidative Diamination of Alkenes with Ureas as Nitrogen Sources:  Mechanistic Pathways in the Presence of a High Oxidation State Palladium Catalyst

Kilian Muñiz, Claas H. Hövelmann, Jan Streuff · Journal of the American Chemical Society · 2007 · 288 citations

, , +14

Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides

John F. Hartwig, Steven Richards, David Barañano et al. · Journal of the American Chemical Society · 1996 · 199 citations

, , +10

1–5 of 39

Authors

132

  1. MS
    Melanie S. Sanford

    University of Michigan, United States

    6 publications · 1K citations

    6

    h-index

  2. MH
    Mónica H. Pérez‐Temprano

    Institut Català d'Investigació Química, Spain

    3 publications · 284 citations

    3

    h-index

  3. DM
    David Milstein

    Weizmann Institute of Science, Israel

    3 publications · 141 citations

    3

    h-index

  4. NM
    Nicole M. Camasso

    University of Michigan, United States

    2 publications · 143 citations

    2

    h-index

  5. PL
    Peng Liu

    University of Pittsburgh, United States

    2 publications · 210 citations

    2

    h-index

1–5 of 132

Institutions

52

  1. University of Michigan

    Ann Arbor, United States

    6 h-index

    19 publications

    2.9K citations

  2. Weizmann Institute of Science

    Rehovot, Israel

    3 h-index

    10 publications

    458 citations

  3. Universitat de Barcelona

    Barcelona, Spain

    3 h-index

    12 publications

    285 citations

  4. Chinese Academy of Sciences

    Beijing, China

    3 h-index

    15 publications

    1.1K citations

  5. University of Tasmania

    Hobart, Australia

    2 h-index

    5 publications

    182 citations

  6. University of Washington

    Seattle, United States

    2 h-index

    6 publications

    99 citations

  7. Polish Academy of Sciences

    Warsaw, Poland

    1 h-index

    1 publications

    12 citations

  8. Utah State University

    Logan, United States

    1 h-index

    3 publications

    165 citations

1–8 of 52

Venues

  1. Journal of the American Chemical Society

    JACS · 12 publications · 1.8K citations

    12

    h-index

  2. Organometallics

    10 publications · 331 citations

    10

    h-index

  3. The Journal of Organic Chemistry

    JOC · 2 publications · 52 citations

    2

    h-index

  4. Chemistry - A European Journal

    2 publications · 129 citations

    2

    h-index

  5. 2

    h-index

1–5