Concepedia

Potential-dependent Rate Constants

Potential-Dependent Rate Constants is a kinetic parameter in electrochemical kinetics that quantifies the rate of an electrode reaction as a function of the applied electrode potential, distinguishing it from potential-independent rate constants by explicitly incorporating the influence of interfacial electric potential on the activation barrier of electron transfer processes.

50

Publications

2.2K

Citations

120

Authors

48

Institutions

Publications per year

2017–2026

5

Parents

Publications

50

Scanning Electrochemical Microscopy. 34. Potential Dependence of the Electron-Transfer Rate and Film Formation at the Liquid/Liquid Interface

Michael Tsionsky, Allen J. Bard, Michael V. Mirkin · The Journal of Physical Chemistry · 1996 · 158 citations

, , +17

Studies in heterogeneous equilibria. Part III. A kinetic theory of reversible oxidation potentials at inert electrodes

J. A. V. Butler · Transactions of the Faraday Society · 1924 · 148 citations

, , +16

On the determination of the value of the charge of the reacting particle and of the constant α from the dependence of the rate of electro-reduction on the potential and concentration of the solution

A Frumkin, O.A. Petry, N.V. Nikolaeva-Fedorovich · Electrochimica Acta · 1963 · 125 citations

, , +12

Electrode potentials and the thermodynamics of isodesmic reactions

Vernon D. Parker, Kishan L. Handoo, Frode Roness et al. · Journal of the American Chemical Society · 1991 · 113 citations

, , +16

Relation between potential and rate parameters for reactions on attractive potential energy surfaces. Application to the reaction HO + O .dblharw. HO2* .fwdarw. H + O2

J. Troe · The Journal of Physical Chemistry · 1986 · 104 citations

, , +16

1–5 of 50

Authors

120

  1. JH
    J.M. Hale

    Electronics and Radar Development Establishment, India

    2 publications · 54 citations

    2

    h-index

  2. RG
    Richard G. Compton

    University of Oxford, United Kingdom

    2 publications · 36 citations

    2

    h-index

  3. SA
    Shigeru Aoyagui

    Tokyo Institute of Technology, Japan

    2 publications · 68 citations

    2

    h-index

  4. KB
    Keith B. Oldham

    Trent University, Canada

    2 publications · 120 citations

    2

    h-index

  5. AJ
    Allen J. Bard

    The University of Texas at Austin, United States

    2 publications · 185 citations

    2

    h-index

1–5 of 120

Institutions

48

  1. Tokyo Institute of Technology

    Tokyo, Japan

    3 h-index

    9 publications

    292 citations

  2. University of Chile

    Santiago, Chile

    2 h-index

    5 publications

    73 citations

  3. Laboratoire d'Electrochimie Moléculaire

    Paris, France

    2 h-index

    4 publications

    310 citations

  4. The University of Texas at Austin

    Austin, United States

    2 h-index

    4 publications

    370 citations

  5. University of Oxford

    Oxford, United Kingdom

    2 h-index

    5 publications

    75 citations

  6. Louisiana State University

    Baton Rouge, United States

    2 h-index

    4 publications

    142 citations

  7. Universidad de Murcia

    Murcia, Spain

    2 h-index

    8 publications

    144 citations

  8. BioElectronics (United States)

    Frederick, United States

    1 h-index

    2 publications

    142 citations

1–8 of 48

Venues

  1. Journal of Electroanalytical Chemistry

    8 publications · 283 citations

    8

    h-index

  2. The Journal of Physical Chemistry

    5 publications · 347 citations

    5

    h-index

  3. Journal of The Electrochemical Society

    JES · 4 publications · 116 citations

    4

    h-index

  4. Electrochimica Acta

    4 publications · 217 citations

    4

    h-index

  5. Journal of the American Chemical Society

    JACS · 3 publications · 170 citations

    3

    h-index

1–5