Concepedia

Nephelauxetic Effect

The Nephelauxetic Effect is a phenomenon in coordination chemistry where the extent of interelectronic repulsion in a metal ion decreases due to orbital overlap with ligands, leading to a reduction in the Racah parameter as a measure of electron correlation in transition metal complexes.

153

Publications

8.1K

Citations

468

Authors

193

Institutions

Publications per year

2017–2026

34

Parents

Publications

153

Silicon-based oxynitride and nitride phosphors for white LEDs—A review

Rong‐Jun Xie, Naoto Hirosaki · Science and Technology of Advanced Materials · 2007 · 987 citations · Full text

, , +17

Calculation of Zero-Field Splittings, g-Values, and the Relativistic Nephelauxetic Effect in Transition Metal Complexes. Application to High-Spin Ferric Complexes

Frank Neese, Edward I. Solomon · Inorganic Chemistry · 1998 · 355 citations

, , +16

Environmental Effects on f–f Transitions. II. “Hypersensitivity” in Some Complexes of Trivalent Neodymium

D.E. Henrie, Gregory R. Choppin · The Journal of Chemical Physics · 1968 · 308 citations

, , +15

Spin-Forbidden Transitions in the Spectra of Transition Metal Ions and Nephelauxetic Effect

M.G. Brik, S.J. Camardello, A.M. Srivastava et al. · ECS Journal of Solid State Science and Technology · 2015 · 261 citations

, , +16

On correlating the frequency of the 7F0 → 5D0 transition in Eu3+ complexes with the sum of ‘nephelauxetic parameters’ for all of the coordinating atoms

Steven T. Frey, William DeW. Horrocks · Inorganica Chimica Acta · 1995 · 250 citations

, , +11

1–5 of 153

Authors

468

  1. CK
    Chr. Klixbüll Jørgensen

    Technical University of Denmark, Denmark

    6 publications · 525 citations

    6

    h-index

  2. MB
    M.G. Brik

    University of Tartu, Estonia

    5 publications · 412 citations

    5

    h-index

  3. AS
    A. Suchocki

    Polish Academy of Sciences, Poland

    4 publications · 323 citations

    4

    h-index

  4. AS
    A.M. Srivastava

    GE Global Research (United States), United States

    4 publications · 401 citations

    4

    h-index

  5. JR
    J. Reedijk

    Leiden University, Netherlands

    4 publications · 279 citations

    4

    h-index

1–5 of 468

Institutions

193

  1. Rijksmuseum

    Amsterdam, Netherlands

    5 h-index

    8 publications

    397 citations

  2. University of Geneva

    Geneva, Switzerland

    4 h-index

    5 publications

    231 citations

  3. GE Global Research (United States)

    Niskayuna, United States

    4 h-index

    5 publications

    662 citations

  4. University of Tartu

    Tartu, Estonia

    4 h-index

    4 publications

    401 citations

  5. Institute of Physics

    Warsaw, Poland

    4 h-index

    7 publications

    694 citations

  6. Polish Academy of Sciences

    Warsaw, Poland

    4 h-index

    10 publications

    694 citations

  7. Kyoto University

    Kyoto, Japan

    4 h-index

    13 publications

    835 citations

  8. Chongqing University of Posts and Telecommunications

    Chongqing, China

    4 h-index

    11 publications

    641 citations

1–8 of 193

Venues

  1. Inorganic Chemistry

    11 publications · 613 citations

    11

    h-index

  2. 10

    h-index

  3. Journal of Luminescence

    6 publications · 288 citations

    6

    h-index

  4. Recueil des Travaux Chimiques des Pays-Bas

    6 publications · 348 citations

    6

    h-index

  5. The Journal of Chemical Physics

    6 publications · 597 citations

    6

    h-index

1–5