Concepedia

Migratory Insertion Intermediates

Migratory Insertion Intermediates is a transient organometallic species in which a ligand migrates from a metal center to an adjacent coordinated unsaturated ligand, forming a new carbon–ligand bond while remaining bound to the metal, thereby representing a key mechanistic step in migratory insertion reactions.

88

Publications

4K

Citations

306

Authors

95

Institutions

Publications per year

2017–2026

11

Parents

Publications

88

Low-Temperature Spectroscopic Observation of Chain Growth and Migratory Insertion Barriers in (α-Diimine)Ni(II) Olefin Polymerization Catalysts

Steven A. Svejda, Lynda K. Johnson, Maurice Brookhart · Journal of the American Chemical Society · 1999 · 302 citations

, , +16

Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes

Francis C. Rix, Maurice Brookhart · Journal of the American Chemical Society · 1995 · 196 citations

, , +14

Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids

Xia Zhao, Jing Jing, Kui Lu et al. · Chemical Communications · 2010 · 151 citations

, , +12

Electronic Effects on the β-Alkyl Migratory Insertion Reaction of <i>para</i>-Substituted Styrene Methyl Palladium Complexes

Francis C. Rix, Maurice Brookhart, Peter S. White · Journal of the American Chemical Society · 1996 · 130 citations

, , +16

Tungsten and molybdenum 2-oxaallyl [.eta.1-(C)-enolate] complexes: functional group transformations, photochemical aldol reactions, and alkyne/carbon monoxide migratory insertion reactions

Elizabeth R. Burkhardt, Jeffrey J. Doney, Robert G. Bergman et al. · Journal of the American Chemical Society · 1987 · 114 citations

, , +16

1–5 of 88

Authors

306

  1. MB
    Maurice Brookhart

    University of North Carolina at Chapel Hill, United States

    5 publications · 752 citations

    5

    h-index

  2. AH
    Anthony Haynes

    University of Sheffield, United Kingdom

    4 publications · 239 citations

    4

    h-index

  3. GJ
    Glenn J. Sunley

    BP (United Kingdom), United Kingdom

    4 publications · 225 citations

    4

    h-index

  4. MB
    Mauro Bassetti

    Istituto di Metodologie Chimiche, Italy

    4 publications · 80 citations

    4

    h-index

  5. RG
    Robert G. Bergman

    University of California, Berkeley, United States

    3 publications · 191 citations

    3

    h-index

1–5 of 306

Institutions

95

  1. Centre National de la Recherche Scientifique

    Paris, France

    5 h-index

    16 publications

    353 citations

  2. University of North Carolina at Chapel Hill

    Chapel Hill, United States

    4 h-index

    13 publications

    1.7K citations

  3. Shanghai Institute of Organic Chemistry

    Shanghai, China

    4 h-index

    16 publications

    559 citations

  4. University of Sheffield

    Sheffield, United Kingdom

    3 h-index

    16 publications

    1.1K citations

  5. Chinese Academy of Sciences

    Beijing, China

    3 h-index

    8 publications

    481 citations

  6. Beijing National Laboratory for Molecular Sciences

    Beijing, China

    3 h-index

    13 publications

    1.2K citations

  7. University of Perugia

    Perugia, Italy

    3 h-index

    6 publications

    293 citations

  8. University of Chinese Academy of Sciences

    Beijing, China

    3 h-index

    20 publications

    678 citations

1–8 of 95

Venues

  1. Organometallics

    31 publications · 1.1K citations

    21

    h-index

  2. Journal of the American Chemical Society

    JACS · 19 publications · 1.6K citations

    18

    h-index

  3. Journal of Organometallic Chemistry

    5 publications · 127 citations

    5

    h-index

  4. Chemistry - A European Journal

    3 publications · 138 citations

    3

    h-index

  5. Angewandte Chemie

    2 publications · 32 citations

    2

    h-index

1–5