Concepedia

Inner-sphere Electron Transfer

Inner-Sphere Electron Transfer is a type of electron transfer reaction in which the electron moves between two metal centers coordinated within a shared ligand framework, distinguished from outer-sphere mechanisms by the formation of a transient covalent bridge that facilitates direct orbital overlap and enables coupling of electronic and structural changes during redox processes.

127

Publications

5.9K

Citations

397

Authors

123

Institutions

Publications per year

2017–2026

26

Parents

Publications

127

Inner-Sphere Heterogeneous Electrode Reactions. Electrocatalysis and Photocatalysis: The Challenge

Allen J. Bard · Journal of the American Chemical Society · 2010 · 396 citations

, , +17

Reversible-Deactivation Radical Polymerization in the Presence of Metallic Copper. A Critical Assessment of the SARA ATRP and SET-LRP Mechanisms

Dominik Konkolewicz, Yu Wang, Mingjiang Zhong et al. · Macromolecules · 2013 · 308 citations

, , +17

TEMPO-Catalyzed Electrochemical C–H Thiolation: Synthesis of Benzothiazoles and Thiazolopyridines from Thioamides

Xiang‐Yang Qian, Shuqi Li, Jinshuai Song et al. · ACS Catalysis · 2017 · 214 citations

, , +13

Reactions of SmI<sub>2</sub> with Alkyl Halides and Ketones:  Inner-Sphere vs Outer-Sphere Electron Transfer in Reactions of Sm(II) Reductants

Rebecca S. Miller, Jennifer M. Sealy, Masangu Shabangi et al. · Journal of the American Chemical Society · 2000 · 182 citations

, , +11

Electron Transfer between Metal Complexes — A Retrospective View (Nobel Lecture)

Henry Taube · Angewandte Chemie International Edition in English · 1984 · 179 citations

, , +17

1–5 of 127

Authors

397

  1. XS
    Xinyu Song

    Shandong University, China

    5 publications · 95 citations

    5

    h-index

  2. YB
    Yuxiang Bu

    Shandong University, China

    5 publications · 95 citations

    5

    h-index

  3. JF
    John F. Endicott

    Wayne State University, United States

    5 publications · 81 citations

    5

    h-index

  4. RV
    Rudi van Eldik

    Friedrich-Alexander-Universität Erlangen-Nürnberg, Germany

    4 publications · 83 citations

    4

    h-index

  5. HT
    Henry Taube

    Stanford University, United States

    4 publications · 216 citations

    4

    h-index

1–5 of 397

Institutions

123

  1. California Institute of Technology

    Pasadena, United States

    4 h-index

    9 publications

    381 citations

  2. Qufu Normal University

    Qufu, China

    4 h-index

    12 publications

    187 citations

  3. Stanford University

    Stanford, United States

    3 h-index

    5 publications

    227 citations

  4. Shandong University

    Jinan, China

    3 h-index

    9 publications

    231 citations

  5. Xiamen University

    Xiamen, China

    3 h-index

    10 publications

    809 citations

  6. Friedrich-Alexander-Universität Erlangen-Nürnberg

    Erlangen, Germany

    3 h-index

    8 publications

    153 citations

  7. University of Illinois Urbana-Champaign

    Urbana, United States

    3 h-index

    7 publications

    137 citations

  8. Korea Advanced Institute of Science and Technology

    Daejeon, South Korea

    3 h-index

    9 publications

    246 citations

1–8 of 123

Venues

  1. Journal of the American Chemical Society

    JACS · 25 publications · 2K citations

    21

    h-index

  2. Inorganic Chemistry

    22 publications · 494 citations

    15

    h-index

  3. ACS Applied Materials & Interfaces

    4 publications · 145 citations

    4

    h-index

  4. Angewandte Chemie International Edition

    4 publications · 162 citations

    4

    h-index

  5. Organometallics

    3 publications · 179 citations

    3

    h-index

1–5