Concepedia

Competing Reductive Elimination

Competing Reductive Elimination is a reaction pathway in organometallic chemistry that, under certain catalytic conditions, occurs in preference to beta-hydride elimination by involving the simultaneous coupling of two ligands bound to a metal center to form a new bond, thereby reducing the metal oxidation state and releasing the coupled product from the coordination sphere.

33

Publications

4K

Citations

99

Authors

40

Institutions

Publications per year

2017–2026

8

Parents

Publications

33

Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center

Guoyin Yin, Xin Mu, Guosheng Liu · Accounts of Chemical Research · 2016 · 745 citations

, , +13

Pathways and Kinetics of Chlorinated Ethylene and Chlorinated Acetylene Reaction with Fe(0) Particles

William A. Arnold, A. Lynn Roberts · Environmental Science & Technology · 2000 · 687 citations

, , +15

Reactivity of Pd(II) Complexes with Electrophilic Chlorinating Reagents:  Isolation of Pd(IV) Products and Observation of C−Cl Bond-Forming Reductive Elimination

Salena R. Whitfield, Melanie S. Sanford · Journal of the American Chemical Society · 2007 · 355 citations

, , +13

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C<sub>2</sub>N<sub>2</sub>O<sub>2</sub>−Ligated Palladium(IV) Complexes

Joy M. Racowski, Allison R. Dick, Melanie S. Sanford · Journal of the American Chemical Society · 2009 · 343 citations

, , +16

Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides

John F. Hartwig, Steven Richards, David Barañano et al. · Journal of the American Chemical Society · 1996 · 199 citations

, , +10

1–5 of 33

Authors

99

  1. MS
    Melanie S. Sanford

    University of Michigan, United States

    6 publications · 1K citations

    6

    h-index

  2. MH
    Mónica H. Pérez‐Temprano

    Institut Català d'Investigació Química, Spain

    3 publications · 284 citations

    3

    h-index

  3. YL
    Yu Lan

    Chongqing University, China

    2 publications · 287 citations

    2

    h-index

  4. JB
    Jean‐Marie Beau

    Centre National de la Recherche Scientifique, France

    2 publications · 110 citations

    2

    h-index

  5. JM
    Joy M. Racowski

    University of Michigan, United States

    2 publications · 439 citations

    2

    h-index

1–5 of 99

Institutions

40

  1. University of Michigan

    Ann Arbor, United States

    6 h-index

    19 publications

    2.9K citations

  2. Centre National de la Recherche Scientifique

    Paris, France

    2 h-index

    6 publications

    330 citations

  3. Institut de Chimie Moléculaire et des Matériaux d'Orsay

    Orsay, France

    2 h-index

    5 publications

    243 citations

  4. Université Paris-Sud

    Orsay, France

    2 h-index

    6 publications

    330 citations

  5. Shanghai Institute of Organic Chemistry

    Shanghai, China

    2 h-index

    9 publications

    3.4K citations

  6. Yale University

    New Haven, United States

    2 h-index

    5 publications

    819 citations

  7. University of Toronto

    Toronto, Canada

    1 h-index

    2 publications

    202 citations

  8. Philipps University of Marburg

    Marburg, Germany

    1 h-index

    4 publications

    48 citations

1–8 of 40

Venues

  1. Journal of the American Chemical Society

    JACS · 10 publications · 1.5K citations

    10

    h-index

  2. Organometallics

    5 publications · 201 citations

    5

    h-index

  3. Chemistry - A European Journal

    3 publications · 140 citations

    3

    h-index

  4. Chemical Science

    3 publications · 278 citations

    3

    h-index

  5. Angewandte Chemie International Edition

    2 publications · 110 citations

    2

    h-index

1–5