Concepedia

Chain-walking Insertion

Chain-Walking Insertion is a migratory insertion mechanism in organometallic chemistry wherein a metal center sequentially relocates along a hydrocarbon chain via repeated β-hydride elimination and reinsertion steps, ultimately enabling functionalization at a non-terminal carbon position.

19

Publications

1.3K

Citations

104

Authors

37

Institutions

Publications per year

2017–2026

10

Parents

Publications

19

Secondary Alkene Insertion and Precision Chain-Walking: A New Route to Semicrystalline “Polyethylene” from α-Olefins by Combining Two Rare Catalytic Events

Tulaza Vaidya, Kristīne Kļimoviča, Anne M. LaPointe et al. · Journal of the American Chemical Society · 2014 · 176 citations · Full text

, , +17

<sup>13</sup>C NMR Analysis of α-Olefin Enchainment in Poly(α-olefins) Produced with Nickel and Palladium α-Diimine Catalysts

Elizabeth F. McCord, Stephan J. McLain, Lissa T.J. Nelson et al. · Macromolecules · 2007 · 120 citations

, , +17

Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols

Margaret J. Hilton, Liping Xu, Per‐Ola Norrby et al. · The Journal of Organic Chemistry · 2014 · 111 citations · Full text

, , +12

Ni(II) α-Diimine-Catalyzed α-Olefins Polymerization: Thermoplastic Elastomers of Block Copolymers

Giuseppe Leone, Massimiliano Mauri, Fabio Bertini et al. · Macromolecules · 2015 · 106 citations

, , +17

Rhodium-Catalyzed Enantioconvergent Isomerization of Homoallylic and Bishomoallylic Secondary Alcohols

Rui‐Zhi Huang, Kai Kiat Lau, Zhaofeng Li et al. · Journal of the American Chemical Society · 2018 · 105 citations

, , +13

1–5 of 19

Authors

104

  1. IK
    Ivan Keresztes

    Cornell University, United States

    2 publications · 251 citations

    2

    h-index

  2. AM
    Anne M. LaPointe

    Cornell University, United States

    2 publications · 251 citations

    2

    h-index

  3. TV
    Tulaza Vaidya

    University of Rochester, United States

    2 publications · 251 citations

    2

    h-index

  4. GW
    Geoffrey W. Coates

    Cornell University, United States

    2 publications · 251 citations

    2

    h-index

  5. KK
    Kristīne Kļimoviča

    University of Houston, United States

    2 publications · 251 citations

    2

    h-index

1–5 of 104

Institutions

37

  1. University of Houston

    Houston, United States

    3 h-index

    11 publications

    978 citations

  2. Cornell University

    Ithaca, United States

    2 h-index

    12 publications

    1.4K citations

  3. Chinese Academy of Sciences

    Beijing, China

    2 h-index

    6 publications

    174 citations

  4. Sun Yat-sen University

    Guangzhou, China

    1 h-index

    8 publications

    648 citations

  5. University of Notre Dame

    Notre Dame, United States

    1 h-index

    1 publications

    111 citations

  6. Institute of Structure of Matter

    Rome, Italy

    1 h-index

    6 publications

    636 citations

  7. Institut Català d'Investigació Química

    Tarragona, Spain

    1 h-index

    8 publications

    384 citations

  8. Jiangsu University of Science and Technology

    Zhenjiang, China

    1 h-index

    7 publications

    140 citations

1–8 of 37

Venues

  1. Macromolecules

    5 publications · 372 citations

    5

    h-index

  2. Journal of the American Chemical Society

    JACS · 4 publications · 452 citations

    4

    h-index

  3. ACS Catalysis

    3 publications · 149 citations

    3

    h-index

  4. Organic Letters

    OL · 1 publications · 21 citations

    1

    h-index

  5. ACS Macro Letters

    1 publications · 53 citations

    1

    h-index

1–5