The Barton Reaction is a photochemical radical reaction in organic chemistry whereby an alkyl nitrite undergoes homolytic cleavage upon ultraviolet irradiation to generate an alkoxyl radical, which subsequently abstracts a hydrogen atom intramolecularly to form a carbon-centered radical that participates in further functionalization, thus enabling remote C–H bond functionalization.
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22
Variants
Barton Nitrite Photolysis
Parents
Publications
145
The Persistent Radical Effect in Organic Synthesis
Armido Studer · Chemistry - A European Journal · 2001 · 378 citations
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1–5 of 426
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140
Centre National de la Recherche Scientifique
Paris, France
8 h-index
21 publications
549 citations
École Polytechnique
Palaiseau, France
5 h-index
8 publications
250 citations
Chinese Academy of Sciences
Beijing, China
4 h-index
11 publications
464 citations
Scripps Research Institute
San Diego, United States
4 h-index
30 publications
4.7K citations
Laboratoire de Synthèse Organique
Palaiseau, France
4 h-index
6 publications
220 citations
Osnabrück University
Osnabrück, Germany
3 h-index
6 publications
106 citations
Shanghai Institute of Organic Chemistry
Shanghai, China
3 h-index
10 publications
414 citations
University College London
London, United Kingdom
3 h-index
7 publications
261 citations
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- The Journal of Organic Chemistry
JOC · 18 publications · 653 citations
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- Journal of the American Chemical Society
JACS · 13 publications · 501 citations
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- Tetrahedron Letters
13 publications · 444 citations
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- Angewandte Chemie International Edition
11 publications · 5.7K citations
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- Organic Letters
OL · 7 publications · 300 citations
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